Loeb also has her own “Wake Up! Brew” coffee line, named after one of her songs on her kids’ album, Camp Lisa. Known for each frame being named after one of her songs, the glasses are designed for your girls. In 2010, she started the Lisa Loeb Eyewear Collection. With her video for “Stay (I Missed You)” rising to such popularity and ubiquity, Loeb, who wears glasses in the vid, has become synonymous with eyewear Perhaps the most obvious career move for the hit single writer is going into the eye frame business. She’s released 10 studio LPs for adults and six more for kids (and families). Her 2016 album, Feel What U Feel, won her the Best Children’s Album Grammy. She’s also starred in shows on The Food Network and E! Children’s MusicĮven more than her appearances on the small and silver screens, Loeb has earned success, acclaim, and a Grammy Award for her work in the children’s music genre. She’s been in movies like Hot Tub Time Machine 2. Loeb, with her recognizable look (thanks to her trademark cat-eye glasses), has been an actor on shows like Gossip Girl and Fuller House. But in more recent times, she’s shifted her efforts to other projects outside of pop music. She also has two albums- Tails and Firecracker-that have been certified Gold. Since then, Loeb has garnered some other moderate musical success, thanks to songs like “Do You Sleep?” in 1996 and “I Do” in 1998. He brought her into the fold and for the movie she released the smash hit, “Stay (I Missed You).” Suddenly, Loeb, walking around an empty loft apartment in the music video for her hit, was a mainstay on MTV. It was Hawke, who was starring in the movie, Reality Bites, that got Loeb to become a star. Foo Fighters legend Dave Grohl and producer Greg Kurstin are back with the 'Hanukkah Sessions' and, to kick off the 2021 installment, the two have unleashed a cover of singer-songwriter Lisa Loeb. But she was also a friend of acclaimed actor Ethan Hawke. Lisa Loeb, born March 11, 1968, was a struggling artist in New York City. Lisa Loeb NEWS Stay Stay I Missed You On day one of Hanukkah this year (Sunday, November 28), acclaimed frontman Dave Grohl released a cover of Lisa Loeb’s hit song, Stay (I. Let’s dive into all the things she’s doing. Previously in a “Where are they Now” segment for Oprah, Loeb shared, “I didn’t really feel very much like a ‘where are they now’ type of person, because I put out an album every year or two, had television shows on pretty major networks, and had done children’s books-you name it“
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Our collection features Men's Renaissance Clothing, Women's Renaissance Clothing, and Children's Renaissance Clothing as well. Researching clothing of the Early Middle Ages is accomplished mainly by examining archeological findings, e.g., by excavating graves. We strive to offer Renaissance clothing that effortlessly transports you to a different time, whether you're donning a Medieval Wedding Dress, or gowns and doublets fit for Queens and Kings. I was once working on an excavation of a Medieval hospital and found a pottery sherd bearing the fingerprint of its maker. History and archaeology are seriously catnip for me. Over the centuries it has been home to many notable people. Its colleges were built with royal and ecclesiastical funds, allowing for their grand scale. However, it is also one of England’s most beautiful medieval cities. I look at their faces and clothes and the past seems closer than I thought. Established in the 12th century, Oxford is perhaps best known for its excellent university. And don't think we've forgotten the peasants and swashbuckling pirates! We have plenty of options for you as well. 10 of the best preserved bodies from the last 5000 years. Our authentically-styled Renaissance clothing truly suits every member of Renaissance society, from Wench Costumes for the wisecracking women with a sharp tongue, to Renaissance Dresses befitting prim and proper princesses. The Old City of Tallinn was established in the early 13th century and has numerous monuments which are several centuries old including the 16th century St. Pearson's brings high quality Renaissance clothing and Medieval costumes to complement everyone's unique taste. The citys old town is the main attraction which has some of the best-preserved medieval monuments in Europe. Renaissance Accessories - Hook-Sashes & Feathers.Renaissance Belts - Leather Accesssories.Vambraces - Gauntlets - Gloves - Bracers The Iron Age is broadly identified as stretching from the end of the Bronze Age around 1200 BC to 500 AD and the beginning of the Medieval period. You can use the adjust tool to change the appearance of your server icon if you want a different look. Drag the ends to scale the size and reposition your element on the canvas. You can use the Elements tool to browse shapes and emojis and use the image search tool to find overlays, graphics, and borders. With the design specifications complete, we can begin customizing the server icon. If your image is already transparent and you need to remove the background color from the canvas, click the transparent icon under Background Color. You can zoom in or out to make precise edits. You can adjust the eraser size, or use the magic wand tool to quickly select and isolate the background from the icon. 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Feel free to use the PNG Maker on any device, like a mobile phone, tablet, or computer.įrom here, you have a few options for opening the editor. All server icons should be 64 x 64 pixels with a PNG file extension, and this free tool easily supports both requirements. Open your browser and visit the PNG Maker by Kapwing to begin creating your Minecraft server icon. first server icon / second server icon / third server icon Step Two: Upload Image to the PNG Maker You can use Pinterest and Google to browse existing server icons for more inspiration. A few ideas to consider are initials representing the server name, custom logos to establish a unique identity, creative symbols, and game characters. Let's begin the tutorial by finding an image for the Minecraft server icon. Step One: Find an Image for Your Minecraft Server Icon Find an image for your Minecraft server icon.All you need to prepare for the tutorial is a browser to access a free online editor and a reliable device to complete each step. We're sharing all the technical aspects, design tips, and upload requirements you need to make a Minecraft server icon with ease without comprising creativity. You have to consider design requirements, file size limits, and format restrictions that may feel constrictive to the creative process. I'm sure you’ll find the perfect video intro maker for your next YouTube upload.In this step-by-step tutorial, we're sharing image requirements and design tips you need to make a Minecraft server icon with ease.Ĭreating server icons isn't easy. Just take a look at the massive collection of intro templates available. Intro Maker has an incredible reputation with thousands of satisfied users. 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To summarize, there is no other place you'll find an intro maker for YouTube that is this easy, fast, or professional.īecause Intro Maker is small (run by one developer!), I can focus on a small niche and offer better quality intro videos than larger video makers that need thousands of templates for every possible video category. There are a few reasons you should consider using Intro Maker as your YouTube intro maker. Why Are My YouTube Intro Maker Video Templates Better Than The Rest? Most video previews take about a minute to render. If you're looking for professional contractors to work on your next project, please don't hesitate to get in touch.This gallery features the types of ceiling boards with the different materials & design options, their pros and cons, and the most popular ceiling board ideas. After another coat of sealer, the repair can be painted to blend with the surrounding décor.Īt R&B Plastering our qualified operatives have worked on countless commercial and domestic installations, and our customers trust their experience. Any gaps or holes need to be filled, or where appropriate a new coat of plaster should be applied to the damaged area. Once thoroughly dry, any loose plaster, paper and paint must be removed, and the affected area should be coated with a suitable primer or sealer. If the damage is less severe, a professional repair procedure should have it looking as good as new. The R&B Plastering team are specialists in this area, and are happy to offer advice. Where the damage has been severe, the affected sections of plasterboard may need to be removed and replaced with new ones. That could mean fixing a hole in a roof or a leaky joint in a water pipe. The first thing to do when repairing a water damaged ceiling is eliminate the cause of the damage. Repair Plasterboard Ceiling From Water Damage Our friendly team of plastering contractors have the knowledge and experience to deal with such situations quickly and efficiently. This can clearly present a danger to health, and in such situations it's a job for a reliable firm of plastering contractors.Īt R&B Plastering we encounter these problems frequently. Mould growth and discolouration can quickly begin to spread throughout the board and surrounding area. Dormant mould spores are activated by exposure to water. Problems can still arise on ceilings that appear to have dried out, due to plasterboard's ability to retain moisture. This is a particular issue where ceilings are concerned, as simple gravity can cause the plasterboard to fall off. Water damaged plasterboard loses its rigidity and will bend, sag and often break. It will easily absorb water and damp, and once saturated takes a long time to dry out. One drawback with plasterboard is the fact that it's very porous. Once fastened in place it is generally 'skimmed' with plaster for a smooth finish, before being papered and/or painted. Its low cost and rigidity makes it an ideal material for lining interior walls and ceilings. The Truth About a Water Damaged Ceilingįor non-DIYers and those outside the building trade, plasterboard is an interior building board made up of white gypsum plaster sandwiched between thick paper. Here we explain how and why a plasterboard ceiling should be repaired. The team at R&B Plastering have more than 20 years of experience on a wide range of plastering projects. If water has had a chance to soak into the plasterboard, it may need replacing. Often the next question is, does it need to be repaired? If contact between water and plasterboard has been brief, the damage could be superficial and may dry out naturally. That's because it's a common problem, particularly on larger buildings such as schools or substantial domestic properties. How To Repair Plasterboard Ceilings After Water Damageįor the building trade, one of the most commonly asked questions following a spell of wet weather is how to repair plasterboard ceiling from water damage. Or click the GUIDE flair to see all Guide posts. Looking for guides? Check out the GUIDE WIKI Please report any rule violations directly to the moderation team. Please post all clan recruiting and searching posts on the recruiting sub: /r/GolfClashClans This rule also applies to callouts for emoji spamming and similar unsportsmanlike behavior. It may not be a cheat, so please check the Known Issues page on the wiki. This can be done via the in-game settings menu within the Golf Clash app or via their support website. Please report any cheats or suspect cheaters directly to Playdemic. Self promotion should be thoughtful, limited and consistently well received by the community. This includes "title only" posts, "I'm quitting" posts, and other posts that won't generate discussion. Low effort content will be removed at the discretion of the moderation team. You can and will be banned without warning. No personal attacks, no excessive profanity, no threats of violence. Please follow the Rediquette rules don't be a jerk. Rediquette is just as important as golf etiquette. You're allowed to have an opinion, but you're not allowed to be a jerk about it. This includes the buying, selling, and trading of accounts or game items. Posting content that encourages, instructs, or asks about cheats, hacks, or other topics that go against the Golf Clash Terms of Service are bannable offenses and will be removed. No hacking, cheating or buying/selling accounts. All content must be related to Golf Clash or this subreddit. Next, pick the format of your choice because most tools offer different format options for the conversion. Click into the address bar of your browser and copy the entire video URL and paste the link into the converter of your choice. Start by navigating YouTube to find the video inputs you want to convert. How Do You Use YouTube to MP3 Converters? MP3 makes it easy to share music files with friends and offers high quality at lower bitrates. The files can be as small as 1/10 the size of lossless files. It also works on almost all playback devices. MP3 format is supported by all modern browsers, making it the best audio file format for browser compatibility. It has become a standard format to exchange files on the web because of its efficient size. MP3 formats are popular as a convenient way to store music on portable devices. When using the YouTube to MP3 converter, you can convert your favorite playlist and enjoy music whenever you wish to do it. You can also use this tool to watch video clips without the internet in offline mode. Most of these Converters are afraid to use. They eliminate restrictions on accessing YouTube files and allow you to create your playlist. YouTube to mp3 converting tools provide access to an unlimited free download of files from YouTube. Some of the features you to look for in a YouTube to mp3 converter and downloader are audio quality, subtitles, batch download using the video URL, and multiple file format compatibility Benefits of YouTube Video URL to Mp3 Conversion tools The most important one is the number of videos you want to convert. When looking for the best YouTube to MP3 converters, there are several factors you may want to consider. What Is The Best YouTube Video For MP3 Converters? It lets you trim MP3 videos, cut songs, and make ringtones with ease. You can then choose the required bitrate and format. Copy the video URL from YouTube that you want to convert and paste it into the converter. This software gives you easy and efficient management of the YouTube to MP3 conversion. On the other hand, carbon tetrachloride is a non-polar molecule, and will exhibit very poor water solubility. In effect, the lower alcohols are half a water molecule. Correlate this behaviour with molecular structure of these compounds. Read More: What is conjunctival flap surgery? What is immiscible with CCl4?ĬCl4 and water are immiscible whereas ethanol and water are miscible in all proportions. Therefore carbon tetrachloride \[CC$hybridization therefore the shape of the molecule is tetrahedral. … Hence the two pairs of bonds in carbon tetrachloride cancel each other resulting in net zero dipole moment. This electronegativity difference between carbon and chlorine makes their bond polar. Following our previous work,32 we have modeled the CCl4 molecule as a rigid, non-polarizable tetrahedron with the carbon atom at its center and a chlorine atom at each one of the vertices. … Does CCl4 have a center of symmetry?ĬCl4 is a tetrahedral molecule having three equivalent C2 and four equivalent C3 symmetry axes. Nine CCl 4 has nine normal vibrational modes in the T d point group these are labelled ν 1 (non-degenerate, A 1 ), ν 2 (doubly-degenerate, E), ν 3 (triply degenerate, T 2 ), and ν 4 (triply degenerate, T 2 ). Chloroform, methylene chloride, acetonitrile and acetone are useful solvents for polar materials. The most common solvents are Carbon Tetrachloride (CCl 4) and Carbon Disulfide (CS 2). Which solvent is best used in infrared spectroscopy? In addition to being toxic, its dissolving power is low. Because carbon tetrachloride does not have any hydrogen atoms, it was historically used in proton NMR spectroscopy. … It is sometimes useful as a solvent for infrared spectroscopy, because there are no significant absorption bands above 1600 cm − 1. Why is carbon tetrachloride used for IR spectroscopy? These moments are modulated by both the rotational and translational motions of the CCl4 molecules. Liquid carbon tetrachloride displays a far-infrared absorption spectrum which is primarily the result of collisional processes involving octapolar and hexadecapolar induction of dipole moments. Lirdprapamongkol K, Svasti J (2000) Alkyl glucoside synthesis using Thai rosewood β-glucosidase. Lang M, Kamrat T, Nidetzky B (2006) Influence of ionic liquid cosolvent on transgalactosylation reactions catalyzed by thermostable β-glycosylhydrolase CelB from Pyrococcus furiosus. Kongsaeree PT, Ratananikom K, Choengpanya K, Tongtubtim N, Sujiwattanarat P, Porncharoennop C, Onpium A, Svasti J (2010) Substrate specificity in hydrolysis and transglucosylation by family 1 β-glucosidases from cassava and Thai rosewood. Kim Y-M, Kim B-H, Ahn J-S, Kim G-E, Jin S-D, Nguyen T-H, Kim D (2009) Enzymatic synthesis of alkyl glucosides using Leuconostoc mesenteroides dextransucrase. Ketudat Cairns JR, Esen A (2010) β-Glucosidases. Kaftzik N, Wasserscheid P, Kragl U (2002) Use of ionic liquids to increase the yield and enzyme stability in the β-galactosidase catalyzed synthesis of N-acetyllactosamine. Can J Chem 80:653–656įerrières V, Bertho J-N, Plusquellec D (1998) A convenient synthesis of alkyl D-glycofuranosiduronic acids and alkyl D-glycofuranosides from unprotected carbohydrates. Enzyme Microb Technol 29:513–520ĭucret A, Carrière J-F, Trani M, Lortie R (2002) Enzymatic synthesis of octyl glucoside catalyzed by almond β-glucosidase in organic media. Biotechnol Prog 17:881–886ĭe Roode BM, van Beek J, van der Padt A, Franssen MCR, Boom RM (2001b) The integrated enzymatic production and downstream processing of hexyl glucoside. Proc Natl Acad Sci USA 97:13555–13560ĭe Roode BM, Oliehoek L, van der Padt A, Franssen MCR, Boom RM (2001a) Downstream processing of enzymatically produced geranyl glucoside. J Nanosci Nanotechnol 19:1172–1175Ĭzjzek M, Cicek M, Zamboni V, Bevan DR, Henrissat B, Esen A (2000) The mechanism of substrate (aglycone) specificity in β-glucosidases is revealed by crystal structures of mutant maize β-glucosidase-DIMBOA, -DIMBOAGlc, and -dhurrin complexes. J Chem Eng Data 52:2166–2170Ĭhung KH, Kim H, Park Y-K, Kim B-H, Kim S-J, Jung S-C (2019) Decyl glucoside synthesized by direct glucosidation of D-glucose over zeolite catalysts and its estrogenicity as non-endocrine disruptive surfactant. Wiley, Weinheim, pp 3–24Īlves LA, Almeida e Silva JB, Giulietti M (2007) Solubility of D-glucose in water and ethanol/water mixtures. In: Carrea G, Riva S (eds) Organic synthesis with enzymes in non-aqueous media. Carbohydr Res 314:177–187Īdlercreutz P (2008) Fundamentals of biocatalysis in neat organic solvents. The N189F dalcochinase mutant and the non-aqueous reaction systems described here show great potential for future commercial production of long-chain alkyl glucosides.Īdasch V, Hoffmann B, Milius W, Platz G, Voss G (1998) Preparation of alkyl α- and β-D-glucopyranosides, thermotropic properties and X-ray analysis. This is the first report of enzymatic synthesis of OG and DG via reverse hydrolysis reactions in ionic liquids and co-solvent mixtures. The identities of OG and DG products were confirmed by HRMS and NMR. On the other hand, the highest yield of DG (64 mol%) was obtained in the reaction containing 0.5 M glucose, 3 unit ml −1 enzyme in 20% (v/v) decanol, 20% (v/v) acetone and 50% (v/v) at 30 ☌. The highest yield of OG (67 mol%) was obtained in the reaction containing 0.5 M glucose, 3 unit ml −1 enzyme in 20% (v/v) octanol and 70% (v/v) at 30 ☌. To synthesize octyl β- d-glucopyranoside (OG) and decyl β- d-glucopyranoside (DG) in three non-aqueous reaction systems, namely organic solvents, ionic liquids and co-solvent mixtures, via reverse hydrolysis reactions catalyzed by the N189F dalcochinase mutant. Previously the brand has teamed up with Historically Black Colleges and Universities (HBCUs), to celebrate and recognize Black community leaders and entrepreneurs. Through this program, the brand aims to encourage the next generation of changemakers who Champion, Hustle, Empower and Win (C.H.E.W.) in their daily pursuit to make their communities better. ' 'Pause Now, Hustle Later' is the latest way that Now and Later is staying true to its commitment to celebrate and amplify Black voices through its #RecognizetheChew program. In recognition of the hustle of entrepreneurship, we're proud to help amplify these small businesses, and to partner with an advocate like La La who not only shares Now and Later's Brooklyn-born origins, but also embodies the brand's bold and vibrant spirit." "According to the Small Business Association, 50 percent of small businesses fail within the first five years due to lack of financial resources. "Now and Later is dedicated to supporting Black leaders and entrepreneurs who are making a positive impact in their communities, which is why we launched the 'Pause Now, Hustle Later' Grant during Black Business Month," said Dave Foldes, Director of Marketing at Now and Later. Kimberly New York, a niche fragrance house featuring artsy, long-lasting scents safe for sensitive skin. Natural Radiant Life, a clean, organic and vegan brand that harnesses the power of 100% whole-food ingredients to replace toxic chemicals in skin care and slow down the visible signs of aging. I See You Wellness, a Brooklyn-based wellness and lifestyle brand that exists to empower communities of color through accessible wellness and radical self-care, specializing in handmade apothecary products and community healing experiences. The lifestyle brand offers a wide variety of loungewear and other casual essentials that are as chic as they are comfy. La La's selected self-care brands include:īuttah Skincare, a line of highly effective products for both women and men, formulated to target everyday skin conditions leaving skin glowing, healthy, and renewed.įancy Homebody, celebrates the idea of embracing a low-key lifestyle, inspiring women to achieve their own version of luxury. "One of my favorite ways to unwind is to enjoy a sweet treat like Now and Later, and now I get to encourage others to take a pause while also shouting out some of my favorite go-to Black-owned companies." I'm always on the go but at the same time, I have to pause and prioritize self-care so that I can show up as my best self," said La La Anthony. "As a mom and businesswoman, the hustle is a part of my daily grind. Each business will receive $10,000 that will help fuel their hustle and aid in their continued growth. Leading into National Black Business month in August, Now and Later is also committing $50,000 in financial support to the selected small businesses through the 'Pause Now, Hustle Later' Grant. To help fans celebrate, La La has unveiled a hand-picked list of Black-owned self-care businesses with products and services that can be added to any self-care routine. Kicking off today in honor of International Self-Care Day, Now and Later and La La are encouraging everyone to take a pause in their day for a moment of self-care. The plan is payable by 24 or 36 approximate equal monthly instalments (exact amounts specified in your statement) depending on the final price of your order. New customers must apply and be approved for a Latitude Gem Visa credit card. Finance is issued by Latitude Financial and is available to approved customers only. ^^ Total price is up to $1,849 which excludes $9.95 monthly account service fee payable to Latitude Financial. Advertised amount subject to approval by Afterpay. 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